Actinide Elements in Catalysis

Rami J. Batrice; Isabell S.R. Karmel; Guy Yardeni; Moris S. Eisen

doi:10.1002/9781119951438.eibc2564

Actinide Elements in Catalysis

Rami J. Batrice, Isabell S.R. Karmel, Guy Yardeni, Moris S. Eisen

Research output: Chapter in Book/Report/Conference proceeding › Entry for encyclopedia/dictionary › peer-review

Abstract

The chemistry of the f‐elements has been marked in recent years by the impressive use of actinides in catalysis. These advances have allowed the actinide community to tailor organoactinide complexes for specific reactivities accomplishing a high level of sophistication. It is important to note that when comparing the actinides to transition or lanthanide block complexes, the actinides will sometimes exhibit complementary reactivities; however, most often, distinctive chemistries are displayed for similar organic transformations. Based on their unique electronic and steric characteristics, it is now possible to design new catalytic transformations. This article highlights the catalytic processes including the activation of small molecules, hydroelementations, coupling reactions, and polymerization/oligomerization of cyclic esters and epoxides.

Original language	English
Title of host publication	Coordination Chemistry Reviews
Publisher	John Wiley & Sons, Ltd
DOIs	https://doi.org/10.1002/9781119951438.eibc2564
State	Published - 21 Jun 2018
Externally published	Yes

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title = "Actinide Elements in Catalysis",

abstract = "The chemistry of the f‐elements has been marked in recent years by the impressive use of actinides in catalysis. These advances have allowed the actinide community to tailor organoactinide complexes for specific reactivities accomplishing a high level of sophistication. It is important to note that when comparing the actinides to transition or lanthanide block complexes, the actinides will sometimes exhibit complementary reactivities; however, most often, distinctive chemistries are displayed for similar organic transformations. Based on their unique electronic and steric characteristics, it is now possible to design new catalytic transformations. This article highlights the catalytic processes including the activation of small molecules, hydroelementations, coupling reactions, and polymerization/oligomerization of cyclic esters and epoxides.",

author = "Batrice, {Rami J.} and Karmel, {Isabell S.R.} and Guy Yardeni and Eisen, {Moris S.}",

year = "2018",

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AU - Batrice, Rami J.

AU - Karmel, Isabell S.R.

AU - Yardeni, Guy

AU - Eisen, Moris S.

PY - 2018/6/21

Y1 - 2018/6/21

N2 - The chemistry of the f‐elements has been marked in recent years by the impressive use of actinides in catalysis. These advances have allowed the actinide community to tailor organoactinide complexes for specific reactivities accomplishing a high level of sophistication. It is important to note that when comparing the actinides to transition or lanthanide block complexes, the actinides will sometimes exhibit complementary reactivities; however, most often, distinctive chemistries are displayed for similar organic transformations. Based on their unique electronic and steric characteristics, it is now possible to design new catalytic transformations. This article highlights the catalytic processes including the activation of small molecules, hydroelementations, coupling reactions, and polymerization/oligomerization of cyclic esters and epoxides.

AB - The chemistry of the f‐elements has been marked in recent years by the impressive use of actinides in catalysis. These advances have allowed the actinide community to tailor organoactinide complexes for specific reactivities accomplishing a high level of sophistication. It is important to note that when comparing the actinides to transition or lanthanide block complexes, the actinides will sometimes exhibit complementary reactivities; however, most often, distinctive chemistries are displayed for similar organic transformations. Based on their unique electronic and steric characteristics, it is now possible to design new catalytic transformations. This article highlights the catalytic processes including the activation of small molecules, hydroelementations, coupling reactions, and polymerization/oligomerization of cyclic esters and epoxides.

U2 - 10.1002/9781119951438.eibc2564

DO - 10.1002/9781119951438.eibc2564

M3 - 百科全书/词典的词条

BT - Coordination Chemistry Reviews

PB - John Wiley & Sons, Ltd

ER -

Actinide Elements in Catalysis

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